Publications

Publications

Publications

Electrolyte Composition-Dependent Product Selectivity in CO2 Reduction with a Porphyrinic Metal–Organic Framework Catalyst

This study found that the copper porphyrin-derived metal-organic framework electrocatalyst FICN-8 can selectively electroreduce CO₂ to CO in anhydrous acetonitrile electrolyte, while formic acid becomes the main product upon the addition of a proton source; mechanistic studies revealed that the proton source changes the reduction pathway, with catalyst-bound hydride (*H) as the key intermediate for formic acid production, highlighting the importance of electrolyte composition for CO₂ reduction product selectivity.

ReadCrystal's contribution： analyze the structural characteristics of FICN-8 through MicroED analysis

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